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Known as radiocarbon dating, this method provides objective age estimates for carbon-based objects that originated from living organisms.The “radiocarbon revolution” made possible by Libby’s discovery greatly benefitted the fields of archaeology and geology by allowing practitioners to develop more precise historical chronologies across geography and cultures.Theoretically, if one could detect the amount of carbon-14 in an object, one could establish that object’s age using the half-life, or rate of decay, of the isotope.In 1946, Libby proposed this groundbreaking idea in the journal Physical Review.Korff predicted that the reaction between these neutrons and nitrogen-14, which predominates in the atmosphere, would produce carbon-14, also called radiocarbon.Libby cleverly realized that carbon-14 in the atmosphere would find its way into living matter, which would thus be tagged with the radioactive isotope.Finally, Libby had a method to put his concept into practice. The circular arrangement of Geiger counters (center) detected radiation in samples while the thick metal shields on all sides were designed to reduce background radiation.

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Top of page The “Curve of Knowns” compared the known age of historical artifacts associated with the Bible, Pompeii, and Egyptian dynasties with their age as determined by radiocarbon dating.

Using this sample and an ordinary Geiger counter, Libby and Anderson established the existence of naturally occurring carbon-14, matching the concentration predicted by Korff. Fortunately, Libby’s group developed an alternative. They surrounded the sample chamber with a system of Geiger counters that were calibrated to detect and eliminate the background radiation that exists throughout the environment.

The assembly was called an “anti-coincidence counter.” When it was combined with a thick shield that further reduced background radiation and a novel method for reducing samples to pure carbon for testing, the system proved to be suitably sensitive.

Top of page Carbon-14 was first discovered in 1940 by Martin Kamen (1913–2002) and Samuel Ruben (1913–1943), who created it artificially using a cyclotron accelerator at the University of California Radiation Laboratory in Berkeley.

Further research by Libby and others established its half-life as 5,568 years (later revised to 5,730 ± 40 years), providing another essential factor in Libby’s concept.

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